刘统信：博士，副教授
Email:liutongxin_0912@126.com

教育与研究经历：

2012- 河南师范大学化学化工学院 副教授
2007-2012 中国科学技术大学 硕博连读
2005-2007 山东师范大学 学士

研究领域与兴趣：

富勒烯化学，绿色有机合成化学，金属有机化学

近年来主持的主要科研项目:

1. 河南省高校科技创新人才支持计划 (18HASTIT006)
2. 富勒烯氮杂衍生物合成，中国博士后科学基金 (2015T80769)
3. 新型富勒烯含氮杂环化合物的合成及其衍生化研究，国家自然科学基金(21302044)
4. 新型富勒烯碳杂稠环衍生物材料的合成与性能研究，国家自然科学基金(U1304524)
5. 利用串联反应构建新型杂环富勒烯衍生物研究，中国博士后科学基金(2013M530339)

代表性论文：

11. Tong-Xin Liu*, Shaoshuai Hua, Nana Ma, Pengling Zhang, Jingjing Bi, Zhiguo Zhang, and Guisheng Zhang*, Reactivity and Synthetic Applications of a-Functionalized Oxime Acetates: Divergent Access to Fulleropyrrolidines and Mono- and Disubstituted 1-Fulleropyrrolines via Copper-Catalyzed Redox-Neutral N-Heteroannulation with [60]Fullerene

Adv. Synth. Catal. 2018, 360, 142. 2018, 360, 142-152.

10. Shilu Xia, Tong-Xin Liu*, Pengling Zhang, Jinliang Ma, Qingfeng Liu, Nana Ma, Zhiguo Zhang, and Guisheng Zhang*, Broad Synthesis of Disubstituted Dihydrofuran-Fused [60]Fullerene Derivatives via Cu(I)/Ag(I)-Mediated Synergistic Annulation Reaction

J. Org. Chem. 2018, 83, 862-870. (Highlighted by Synfacts 2018, 14, 369.)

9. Di Chao, Tong-Xin Liu*, Nana Ma, Pengling Zhang, Zheng Fu, Jinliang Ma, Qingfeng Liu, Fengjin Zhang, Zhiguo Zhang and Guisheng Zhang*, Silver(I)-mediated three-component annulation reaction of [60]fullerene, sulfonylhydrazones, and nitriles: leading to diverse disubstituted [60]fullerene-fused dihydropyrroles

Chem. Commun. 2016, 52, 982-985.

8. Tong-Xin Liu*, Jinliang Ma, Di Chao, Pengling Zhang, Nana Ma, Qingfeng Liu, Lei Shi, Zhiguo Zhang, and Guisheng Zhang*, Synthesis of C₆₀-Fused Tetrahydrocarbazole/Dibenzothiophene/ Benzothiophene and Dibenzofuran Derivatives via Metal-Free Oxidative Dehydrogenative Carboannulation

Org. Lett. 2016, 18, 4044-4047.

7. Tong-Xin Liu*, Jinliang Ma, Di Chao, Pengling Zhang, Qingfeng Liu, Lei Shi, Zhiguo Zhang and Guisheng Zhang*, AgNO₂-mediated cleavage of the N–N bond of sulfonylhydrazones and oxygen transfer: access to fulleroisoxazolines via radical cyclization with [60]fullerene

Chem. Commun. 2015, 51, 12775-12778.

6. Tong-Xin Liu*, Zhenbei Zhang, Qingfeng Liu, Pengling Zhang, Penghao Jia, Zhiguo Zhang, and Guisheng Zhang*, Synthesis of [60]Fullerene-Fused Tetrahydroazepinones and Azepinonimines via Cu(OAc)₂-Promoted N-Heteroannulation Reaction

Org. Lett. 2014, 16, 1020-1023.



5. Tong-Xin Liu*, Yuquan Liu, Di Chao, Pengling Zhang, Qingfeng Liu, Lei Shi, Zhiguo Zhang, and Guisheng Zhang*, Iron-Mediated Internal-Oxidant Relay Cascade Reaction: Strategy to Synthesize Fullerenooxazoles and Hydroxyfullerenyl Amides

J. Org. Chem. 2014, 79, 11084-11090.

4. Tong-Xin Liu, Fa-Bao Li, Dian-Bing Zhou, and Guan-Wu Wang*, Ferric Perchlorate Promoted Reaction of [60]Fullerene with N−Sulfonyl Aldimines: Synthesis and Functionalization of Fulleroxazolidines

J. Org. Chem. 2015, 80, 11986-11992.

3. Tong-Xin Liu, Tao Wei, San-E Zhu, Guan-Wu Wang*, Mingzhi Jiao, Shangfeng Yang*, Faye L. Bowles, Marilyn M. Olmstead*, and Alan L. Balch*. Azide Addition to an Endohedral Metallofullerene: Formation of Azafulleroids of Sc₃N@I_h-C₈₀

J. Am. Chem. Soc. 2012, 134, 11956-11959.

2. Tong-Xin Liu, Fa-Bao Li, and Guan-Wu Wang, Synthesis of [60]Fullerene-Fused Tetrahydronaphthalene and Indane Derivatives via a Pathway Switched by Aluminum Chloride

Org. Lett. 2011, 13, 6130-6133.

1. Guan-Wu Wang*, Tong-Xin Liu, Mingzhi Jiao, Nan Wang, San-E Zhu, Chuanbao Chen, Shangfeng Yang*, Faye L. Bowles, Dr. Christine M. Beavers, Marilyn M. Olmstead*, Brandon Q. Mercado, and Alan L. Balch*, The Cycloaddition Reaction of I_h-Sc₃N@C₈₀ with 2-Amino-4,5- diisopropoxybenzoic Acid and Isoamyl Nitrite to Produce an Open-Cage Metallofullerene,

Angew. Chem., Int. Ed. 2011, 50, 4658-4662.